LQ-TAHP Tert-amyl hydroperoxide 3425-61-4

ItemContent
Product NameInitiator LQ-TAHP
Chemical NameTert-amyl hydroperoxide
Molecular FormulaC₅H₁₂O₂
Molecular Weight104.1
Theoretical Active Oxygen Content15.36%
CAS No.3425-61-4
UN No.3107
IMDG Classification5.2 (Class 5.2 Liquid Organic Peroxide, Type E, Dangerous Goods Packaging)

Major Decomposition Products

Decomposition Product
Methane
Acetone
Tert-pentanol

Safety Indicators

Half-LifeTemperature
0.1 hour202°C
1 hour183°C
10 hours165°C

Thermal Stability Data

Thermal Stability ParameterTemperature
Self-accelerating Decomposition Temperature (SADT)80°C
Critical Temperature (Tem)75°C
Recommended Storage Temperature (Ts max)--/15°C

Activation Energy

Activation Energy (E)Details
E (KJ/mol)10.92-11.18% (Active Oxygen Content)

Applications

ApplicationDetails
Polymerization InitiatorUsed in free radical polymerization, including emulsion polymerization, water-phase polymerization, and curing processes. Can also be used in styrene and styrene copolymers (SAN, ABS, etc.), acrylic acid, methacrylic acid, and vinyl chloride polymerization.

Packaging and Transportation

ItemDetails
Standard Packaging25 kg or 180 kg polyethylene plastic drums. IBC packaging available with caution on SADT being 50°C and Tem 55°C.
Transport RegulationsTransport conforms to IMDG 5.2, UN No. 3107 (Class 5.2 Liquid Organic Peroxide).

Shelf Life

Shelf Life (Storage Conditions)Details
Shelf LifeProduct quality guaranteed for 6 months if stored according to manufacturer instructions.

Storage Instructions

PrecautionDescription
Storage TemperatureStore at temperatures not exceeding 35°C. Avoid exceeding critical temperature.
Storage EnvironmentStore away from heat sources, flames, acids, reducing agents, and heavy metals (e.g., accelerators, metal soaps).
HandlingKeep packaging sealed and in a well-ventilated area. Avoid opening packaging or handling in storage.

Fire Protection

Fire ProtectionDescription
Small Fire HandlingUse dry powder or CO₂ extinguishers. Apply large amounts of water to prevent re-ignition.
Large Fire HandlingFor large fires, use a large water stream from a safe distance.

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