Item | Content |
---|---|
Product Name | Initiator LQ-TBPEH |
Chemical Name | Tert-Butyl peroxy-2-ethylhexanoate |
Molecular Formula | C₁₂H₁₄O₃ |
Molecular Weight | 216.4 |
Pure Peroxide Active Oxygen Content | 7.40% |
CAS No. | 3006-82-4 |
UN No. | 3113 |
Level | 5.2 |
Classification | C-type liquid organic peroxide, temperature-controlled transport, rail and air transport prohibited |
Properties
Property | Description |
---|---|
Appearance | Colorless, transparent liquid |
Color | 20 APHA |
Active Content | 97% min |
TBHP Content | 0.1% max |
Inorganic and Organic Hydrolyzable Chlorides | 100 mg/kg max |
Safety Indicators
Half-Life | Temperature |
---|---|
0.1 hour | 113℃ |
1 hour | 91℃ |
10 hours | 72℃ |
Thermal Stability Data | Temperature |
---|---|
Self-accelerating Decomposition Temperature (SADT) | 35℃ |
Critical Temperature (Tem) | 25℃ |
Control Temperature (Tc) | 20℃ |
Storage Temperature (Tsmax/TSmin) | -30/20℃ |
Activation Energy (E) | 124.9 kJ/mol |
Applications
Application | Description |
---|---|
Polymerization Initiator | Common initiator for ethylene polymerization, suitable for batch and tubular processes. Also suitable for acrylate and methacrylate polymerization, with a temperature range of 80-150°C. |
Styrene Polymerization | Superior activity compared to BPO for styrene polymerization; can be used in combination with other peroxides like TBPB and TBEC. |
Vinyl Acetate (EVA) Copolymer | Important initiator for EVA copolymerization. |
Curing Agent for Unsaturated Polyester | High-temperature curing agent for unsaturated polyesters, with curing temperatures of 120-160°C. Primarily used in UP hot press molding (DMC, BMC) processes, also used with cobalt-based accelerators for air-dry coatings and filament winding processes at 60°C. |
Packaging and Transport
Packaging | Description |
---|---|
Standard Packaging | 20 kg polyethylene packaging, custom packaging available upon request. |
Transport | LQ-TBPEH is classified as a Class 5.2 liquid organic peroxide, temperature-controlled transport, rail and air transport prohibited. |
Storage Instructions
Precaution | Description |
---|---|
Storage Conditions | Store in a cool, ventilated space, with a warehouse temperature not exceeding 20°C. |
Storage Precautions | Keep away from fire, heat sources, acids, reducing agents, flammable substances, and combustibles. |
Handling Precautions | Ensure storage facilities, lighting, and ventilation are explosion-proof, with switches located outdoors. Handle with care to avoid container damage and vibration. Personal protective equipment should be used during handling. |
Fire Protection
Precaution | Description |
---|---|
Small Fire Handling | Use foam or dry powder fire extinguishers for small fires. |
Large Fire Handling | Evacuate to a safe distance and use a water hose to extinguish. Notify fire services for further handling. |